15 Celebrities Who Shared Sizzling Chemistry On And Off-Screen

#1 Alexis Bledel and Vincent Kartheiser in 'Mad Men'.

Alexis and Vincent met on the set of Mad Men for the first time and fell in love with each other. The couple married in 2014 and have been living happily ever after.

AMC | AMC

#2 Julianna Margulies and George Clooney had the hots for one another in 'ER'.

Who could forget the sizzling chemistry between Julianna and Geroge during the ER days? According to Julianna, that kind of chemistry only occurs when both actors have a crush on one another.

NBC | NBC

#3 Eva Mendes and Ryan Gosling in 'The Place Beyond The Pines'.

Ryan and Eva also met for the first time on the set of The Place Beyond the Pines and given their hot chemistry, the couple got into a relationship very soon. 

Now, the couple has two beautiful children together.

Focus Features | Focus Features

#4 Jenna Dewan and Channing Tatum in 'Step Up'.

Channing and Jenna had our hearts racing in the cult classic film Step Up. They got married in 2009 and also welcomed their first child together. However, their love story was not meant to be forever as they divorced in February of 2020.

Giphy | Lionsgate Home Entertainment

#5 Robert Pattinson and Kristen Stewart in the 'Twilight' saga.

Kristen Stewart broke millions of young girls' hearts all over the world when news of her relationship with Twilight co-star Robert Pattinson was confirmed. Kristen also became one of the most hated celebrities in Hollywood after rumors surfaced that she cheated on him.

Summit Entertainment | Summit Entertainment

#6 Jennifer Lopez and Ben Affleck in 'Gigli'.

There was a time Ben Affleck and J-Lo were the most talked about couple in Hollywood. Their film Gigli was a disaster, but the chemistry sure something to remember for a long time to come. 

instagram | @jlo

#7 Shane West and Mandy Moore in 'A Walk To Remember'.

"There was chemistry," Shane told Vulture. "I think we both had a little bit of a crush, but then we were just there for each other in the most honest and purest of ways. That sounds incredibly corny, but it's true and rare."

Giphy | GoPlay

#8 Brad Pitt and Angelina Jolie in 'Mr. & Mrs. Smith'.

Brad and Angelina had the chance to get close to each other on the set of Mr. & Mrs. Smith. 

Reports were later confirmed, resulting in Brad's divorce from his then-current wife, Jennifer Aniston.

20th Century Fox | 20th Century Fox

#9 Rachel McAdams and Ryan Gosling in 'The Notebook'.

Anyone who has watched The Notebook would know that the chemistry between Ryan and Rachel was too good to not be true. Our suspicions were confirmed not long after that Ryan and Rachel were dated, however they broke up not long after the film's release.

Giphy

#10 Ben Affleck and Jennifer Garner in 'Daredevil'.

The only good thing to come out of Daredevil film was Ben Affleck's and Jennifer Garner's marriage. The couple stayed together for a good many years before finally calling it quits in October of 2018.

20th Century Fox | 20th Century Fox

#11 Sarah Michelle Gellar and Freddie Prinze Jr. in 'I Know What You Did Last Summer'

Freddie and Michelle had amazing on-screen chemistry even though their characters weren't romantically linked. The couple began dating soon and have been happily married since 2002.

Giphy | Coolidge Corner Theatre

#12 Minnie Driver and Matt Damon in 'Good Will Hunting'.

Minnie Driver and Matt Damon fell for each other during the shooting and the duo even dated for a while before calling it quits.

Miramax Films | Miramax Films

#13 Rachel Bilson and Adam Brody in 'The O.C.'

Fans of The O.C. found it all but impossible to not fall in love with Summer and Seth. It would appear that Adam Brody and Rachel Bilson reciprocated our feelings, as the couple dated for three years before going their separate ways.

Giphy

#14 Tom Holland and Zendaya in the 'Spider-Man' franchise.

Nowadays everyone's favorite Hollywood couple is Tom Holland and Zendaya because of the couple's sizzling chemistry in the Spider-Man franchise. Their relationship began in the first Spider-Man film and is still going strong.

Sony Pictures | Sony Pictures

#15 Andrew Garfield and Emma Stone in 'The Amazing Spider-Man'.

Andrew and Emma were warned by the studio executives to not get linked with each other romantically, but they went against all odds and began dating shortly.  Though their relationship didn't last long and the two have been good friends since then.

Sony Pictures | Sony Pictures